|本期目录/Table of Contents|

[1]王领民,张全,刘斯雨,等.离子液体介导玉米秸秆制备5-羟甲基糠醛[J].生物加工过程,2017,15(03):53-58.[doi:10.3969/j.issn.1672-3678.2017.03.009]
 WANG Lingmin,ZHANG Quan,LIU Siyu,et al.Preparation of 5-hydroxymethylfurfural from corn stover mediated by ionic liquids[J].Chinese Journal of Bioprocess Engineering,2017,15(03):53-58.[doi:10.3969/j.issn.1672-3678.2017.03.009]
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离子液体介导玉米秸秆制备5-羟甲基糠醛()
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《生物加工过程》[ISSN:1672-3678/CN:32-1706/Q]

卷:
15
期数:
2017年03期
页码:
53-58
栏目:
出版日期:
2017-05-30

文章信息/Info

Title:
Preparation of 5-hydroxymethylfurfural from corn stover mediated by ionic liquids
文章编号:
1672-3678(2017)03-0053-06
作者:
王领民1张全1刘斯雨2关浩1高慧鹏1
1.中国石油化工股份有限公司 抚顺石油化工研究院生物化工部,辽宁 抚顺 113001; 2.中国石油化工股份有限公司 镇海炼化分公司,浙江 宁波 315200
Author(s):
WANG Lingmin1ZHANG Quan1LIU Siyu2GUAN Hao1GAO Huipeng1
1. Department of Biology & Chemical Engineering,Fushun Research Institute of Petroleum and Petrochemicals, Sinopec,Fushun 113001,China; 2. Zhenhai Refining and Chemical Company,Sinopec,Ningbo 315200,China
关键词:
离子液体 玉米秸秆 5-羟甲基糠醛
分类号:
TQ352.6
DOI:
10.3969/j.issn.1672-3678.2017.03.009
文献标志码:
A
摘要:
以玉米秸秆为原料,采用离子液体([BMIM]Cl)与二甲基亚砜(DMSO)为溶剂,氯化铬和浓硫酸为催化剂制备5-羟甲基糠醛(5-HMF)。通过考察反应时间、温度、催化剂加入量和固液比等条件,以获得制备5-HMF的最优反应条件,反应产物由高效液相色谱分析。结果表明:酸解后的秸秆,在150 ℃、固液比为3.8%、m([BMIM]Cl)/m(DMSO)=1、硫酸和氯化铬的质量分数分别6.7%和13.3%(相对于秸秆)的条件下反应80 min时,5-HMF产率较高,为53.3%。

参考文献/References:

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备注/Memo

备注/Memo:
收稿日期:2017-03-30
基金项目:中国石油化工股份有限公司委托开发项目(414057)
作者简介:王领民(1977—),男,河南泌阳人,高级工程师,研究方向:生物质微生物转化,E-mail:wanglingmin.fshy@sinopec.com.
更新日期/Last Update: 2017-05-30